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Comparative Mechanical and Thermal Properties of Epoxy Matrix Composite Reinforced with Coco Peat and Coconut Shell Charcoal Fillers for Automotive Brake Friction Applications

Al Ichlas Imran , Nanang Endriatno , Januar Parlaungan Siregar , Mohd Ruzaimi Mat Rejab , Sambodo Arif Wibowo , Tezara Cionita , Deni Fajar Fitriyana

Abstract

Developing epoxy-based composites reinforced with natural materials has become a significant concern in supporting friction materials and sustainable automotive industries. Coco peat and coco shell charcoal are coconut wastes that have the potential as natural fillers to support the mechanical properties of friction material composites while supporting the reduction of biomass waste. This study aims to evaluate the effect of weight fraction variation of coco peat and coco shell charcoal on composite mechanical and thermal properties. Specimens were prepared using the hand lay-up method with 5%, 10%, and 15% filler weight fractions. Mechanical tests were conducted, including tensile test, bending test, Rockwell hardness, and Charpy impact. Results show that the addition of 5% coco peat increased the tensile strength to 28.36 MPa and impact strength to 123.33 J/m², while coco shell charcoal at 10% recorded the highest flexural strength of 36.10 MPa and hardness of 93.66 HRB. However, increasing the filler concentration caused a decrease in tensile and impact strength due to the formation of voids, agglomeration, and micro-cracks. These findings confirm that coco peat is effective for tensile and impact strengthening at low fractions. In contrast, coco shell charcoal improves flexural strength and produces higher hardness values than the commercial brake pad product (59.59-66.90 HRB). Furthermore, the composite with 5% coco shell charcoal showed good thermal stability with a final residue value of 3.83%. Further studies can focus on surface modification of fillers, hybrid composites, and evaluation of tribological properties and the environment to promote applications in the automotive industry sector.


 

Keywords

Friction material composite; Natural filler; Coco peat; Coco shell charcoal; Mechanical properties; Thermal properties

References

  1. A. I. Imran et al., “Advancements in sustainable material development: A Comprehensive review of coir fiber and its composites,†Mech. Eng. Soc. Ind., vol. 4, no. 3, pp. 415–454, 2024, doi: 10.31603/mesi.12556.
  2. R. S. Juan, C. Kurniawan, J. Marbun, and P. Simamora, “Mechanical properties of brake pad composite made from candlenut shell and coconut shell,†J. Phys. Conf. Ser., vol. 1428, pp. 1–6, 2020, doi: 10.1088/1742-6596/1428/1/012018.
  3. A. Kholil, S. T. Dwiyati, R. Wirawan, and M. Elvin, “Brake Pad Characteristics of Natural Fiber Composites from Coconut Fibre and Wood Powder,†in Journal of Physics : Conference Series, iopscience.iop.org, 2021, pp. 1–7. doi: 10.1088/1742-6596/2019/1/012068.
  4. E. da S. B. Ferreira, C. B. B. Luna, E. M. Araujo, D. D. Siqueira, and R. M. R. Wellen, “Polypropylene/wood powder composites: Evaluation of PP viscosity in thermal, mechanical, thermomechanical, and morphological characters,†J. Thermoplast. Compos. Mater., vol. 35, no. 1, pp. 71–92, 2022, doi: https://doi.org/10.177/0892705719880958.
  5. A. I. Imran et al., “Opportunities and challenges in the sustainable integration of natural fibers and particles in friction materials for eco-friendly brake pads,†Mech. Eng. Soc. Ind., vol. 4, no. 3, pp. 337–367, 2024, doi: 10.31603/mesi.12271.
  6. A. Bayu et al., “Utilization of Bamboo Powder in The Production of Non-Asbestos Brake Pads : Computational Bibliometric Literature Review Analysis and Experiments to Support Sustainable Development Goals ( SDGs ),†Automot. Exp., vol. 7, no. 1, pp. 111–131, 2024, doi: 10.31603/ae.11109.
  7. T. Cionita et al., “Mechanical Characteristics of Biocomposites Based on Rice Husk Reinforced Recycled Polypropylene,†Int. J. Integr. Eng., vol. 16, no. 2, pp. 278–287, 2024, doi: 10.30880/ijie.2024.16.02.029.
  8. T. Balamurugan, G. K. Ayyadurai, H. Trilaksana, and G. Palani, “Enhancing mechanical performance of flax fiber/vinyl ester composites with coconut husk char: a sustainable approach for hybrid composite material,†Biomass Convers. Biorefinery, 2024, doi: https://doi.org/10.1007/s13399-024-05695-y.
  9. T. M. N. Tran, P. MN, D. W. Lee, and J. I. Song, “Effect of hybrid ecoâ€friendly reinforcement and their size on mechanical and flame retardant properties of polypropylene composites for technical applications,†Polym. Compos. Compos., vol. 45, no. 3, pp. 2427–2443, 2024, doi: https://doi.org/10.1002/pc.27930.
  10. B. R. Freitas et al., “Characterization of coir fiber powder (cocos nucifera L.) as an environmentally friendly inhibitor pigment for organic coatings,†J. Mater. Res. Technol., vol. 19, pp. 1332–1342, 2022, doi: 10.1016/j.jmrt.2022.05.098.
  11. K. Manjunathan, P. Nagarajan, K. Palanivel, A. R. B. Rudrakotti, A. Palanivel, and M. Megaraj, “Characterization of medium-density hybrid fiberboards using saw-dust and coco peat with UF resin,†in AIP Conference Proceedings, AIP Publishing, 2024. doi: https://doi.org/10.1063/5.0241701.
  12. N. Fitriadi, M. Rizal, and S. Fonna, “Physical And Thermal Characteristics Of Coco Peat Fibre Reinforced Polyurethane Composite For Insulation Box In Marine Application,†J. Eng. Sci. Technol., vol. 17, no. 6, pp. 3787–3799, 2022.
  13. N. S. Sadeq, Z. G. Mohammadsalih, and R. Mohammed, “The influence of particle size on the mechanical performance of epoxy coir composites,†J. Univ. Coll. Basic Educ. Al-Mustansiriya, vol. 22, pp. 1–11, 2022, doi: DOI: https://doi.org/10.35950/cbej.v22iSI.5911.
  14. L. K. Sriramamurthy et al., “Experimental and statistical evaluation of the mechanical performance of (Jute and Cocopeat) plant and (Silk) animal-based hybrid fibers reinforced with epoxy polymers,†J. Nat. Fibers, vol. 19, no. 16, pp. 12664–12675, 2022, doi: https://doi.org/10.1080/15440478.2022.2073501.
  15. K. R. Pai, K. S. Lokesh, D. S. Mayya, J. R. N. Kumar, and A. M. Hebbale, “Experimental study on preparation and mechanical characteristics of jute/silk/coco-peat reinforced with epoxy polymers,†Mater. Today Proc., vol. 46, no. 7, pp. 2764–2769, 2021, doi: https://doi.org/10.1016/j.matpr.2021.02.511.
  16. G. Chandrasekhar and V. Rangari, “Coconut Shell Derived Carbon Reinforced Polymer Composite Films for Packaging Applications,†in Biocarbon Polymer Composites, Bentham Science Publishers, 2023, pp. 127–140. doi: DOI: 10.2174/9789815196689123010011.
  17. S. Darmo and R. Sutanto, “Influence of Coconut Shell Charcoal Powder Filler on the Tribological Properties of Natural Fiber Reinforced Polimer Compocite,†Int. J. Adv. Eng. Manag., vol. 3, no. 5, pp. 382–388, 2021, doi: 10.35629/5252-0305382388.
  18. B. Rajadurai and J. Chandradass, “Mechanical, thermal, and morphological characterization of polylactic acid composites reinforced with coconut shell activated carbon,†Mater. Res. Express, vol. 11, no. 11, 2024, doi: https://doi.org/10.1088/2053-1591/ad95e6.
  19. M. E. G. F. Agcaoili and A. K. G. Tapia, “Morphological, optical and AC electrical properties of polyaniline emeraldine salt/poly (vinyl acetate)/coconut shell charcoal sheets,†in Materials Today: Proceedings, Elsevier, 2020, pp. 1849–1852. doi: https://doi.org/10.1016/j.matpr.2020.05.186.
  20. P. Prabhu, D. Jayabalakrishnan, V. Balaji, K. Bhaskar, T. Maridurai, and V. R. A. Prakash, “Mechanical, tribology, dielectric, thermal conductivity, and water absorption behaviour of Caryota urens woven fibre-reinforced coconut husk biochar toughened wood-plastic composite,†Biomass Convers. Biorefinery, vol. 14, no. 1, pp. 109–116, 2024, doi: https://doi.org/10.1007/s13399-021-02177-3.
  21. O. V Potadar and G. S. Kadam, “Preparation and testing of composites using waste groundnut shells and coir fibres,†in Procedia Manufacturing, Elsevier, 2018, pp. 91–96. doi: https://doi.org/10.1016/j.promfg.2018.02.013.
  22. G. B. Nyior, S. A. Aye, and S. E. Tile, “Study of mechanical properties of raffia palm fibre/groundnut shell reinforced epoxy hybrid composites,†J. Miner. Mater. Charact. Eng., vol. 6, no. 2, pp. 179–192, 2018, doi: 10.4236/jmmce.2018.62013.
  23. ASTM D638, “Standard Test Method for Tensile Properties of Plastics,†in ASTM Standards, vol. 08, 2014, pp. 1–16.
  24. ASTM D6110, “Standard Test Methods for Determining the Charpy Impact Resistance of Notched,†in ASTM Standards, 1998.
  25. T. D. Sutanto, I. Gustian, and C. Banon, “Optimum Cocopeat grain size of particle board based on Cocopeat and liquid rubber compound,†Int. J. Chem. Biochem. Sci., vol. 25, no. 14, pp. 60–66, 2024, doi: DOI:10.4038/TARE.V18I1.5324.
  26. B. Balkhaya and N. Fitriadi, “Mechanical Characteristics Of Composite Materials Made From Polyester Resin Mixed With Cocopeat On Static Loads,†J. Inotera, vol. 9, no. 1, pp. 170–177, 2024, doi: DOI: https://doi.org/10.31572/inotera.Vol9.Iss1.2024.ID335.
  27. J. George, D. Jung, and D. Bhattacharyya, “Improvement of electrical and mechanical properties of PLA/PBAT composites using coconut shell biochar for antistatic applications,†Appl. Sci., vol. 13, no. 2, p. 902, 2023, doi: https://doi.org/10.3390/app13020902.
  28. S. Kumar and S. K. Ghosh, “Porosity and tribological performance analysis on new developed metal matrix composite for brake pad materials,†J. Manuf. Process., vol. 59, pp. 186–204, 2020, doi: https://doi.org/10.1016/j.jmapro.2020.09.053.
  29. R. Vijay, S. Manoharan, S. Arjun, A. Vinod, and D. Singaravelu, “Characterization of Silane-Treated and Untreated Natural Fibers from Stem of Leucas Aspera,†J. Nat. Fibers, vol. 18, no. 12, pp. 1957–1973, 2021, doi: 10.1080/15440478.2019.1710651.
  30. L. G. Babu, “Influence of benzoyl chloride treatment on the tribological characteristics of Cyperus pangorei fibers based non-asbestos brake friction composites,†Mater. Res. Express, vol. 7, pp. 1–11, 2019, doi: 10.1088/2053-1591/ab54f1.
  31. N. H. A. Norhasnan, M. Z. Hassan, A. F. M. Nor, S. A. Zaki, and ..., “Physicomechanical properties of rice husk/coco peat reinforced acrylonitrile butadiene styrene blend composites,†Polymers (Basel)., 2021.
  32. F. Feni, M. Jahan, F. Dawan, S. Ibekwe, G. Li, and P. Mensah, “Enhancing the mechanical performance of carbon fiber reinforced polymer using carbonized coconut shell particles,†Mater. Today Commun., vol. 33, pp. 1–9, 2022, doi: https://doi.org/10.1016/j.mtcomm.2022.104727.
  33. K. Bhaskar, D. Jayabalakrishnan, M. V. Kumar, S. Sendilvelan, and M. Prabhahar, “Analysis on mechanical properties of wood plastic composite,†in Materials Today: Proceedings, Elsevier, 2021, pp. 5886–5891. doi: https://doi.org/10.1016/j.matpr.2020.08.570.
  34. U. C. Mark, I. C. Madufor, H. C. Obasi, and U. Mark, “Influence of filler loading on the mechanical and morphological properties of carbonized coconut shell particles reinforced polypropylene composites,†J. Compos. Mater., vol. 54, no. 3, pp. 397–407, 2020, doi: https://doi.org/10.1177/0021998319856070.
  35. A. I. Imran et al., “Exploring the Potential of Sago Residuefor Eco-Friendly Construction Materials,†BioResources, vol. 20, no. 3, pp. 1–34, 2025, doi: 10.15376/biores.20.3.Imran.
  36. M. Işık, N. Özmeral, G. Ahmetli, and M. S. Kalem, “Effect of various aging conditions and treatment methods on thermal degradation of coffee waste/epoxy composites,†Ind. Crops Prod., vol. 220, pp. 1–14, 2024, doi: https://odoi.org/10.1016/j.indcrop.2024.119115.
  37. S. Bahlouli, A. Belaadi, A. Makhlouf, H. Alshahrani, and ..., “Effect of Fiber Loading on Thermal Properties of Cellulosic Washingtonia Reinforced HDPE Biocomposites,†Polymers (Basel)., vol. 15, no. 13, 2023, doi: https://doi.org/10.3390/polym15132910.
  38. E. Vengadesan, T. Arunkumar, S. Muralidharan, K. Debnath, H. Dutta, and K. Kadirgama, “Hybrid Bio-composites Reinforced with Natural Wood Saw Dust and Eco-friendly Graphite: Evaluation of Physical, Mechanical, and Thermal Properties,†Fibers Polym., vol. 26, pp. 1–22, 2025, doi: https://doi.org/10.1007/s12221-025-00848-w.
  39. L. I. M. G. Etsa and I. G. K. Puja, “Effect of curing time on the mechanical properties of composite coconut shell charcoal nanocarbon reinforced epoxy,†in Journal of Physics: Conference Series, IOP Publishing, 2025, p. 12052. doi: DOI 10.1088/1742-6596/2972/1/012052.

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